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Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr2sub>O3sub> Systemwith Al2sub>O3sub> and Cr2sub>O3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Strategic Study of CAE 2004, Volume 6, Issue 6, Pages 63-67

Abstract:

The thermodynamic calculation and analysis of combustion synthesis reaction of Al - Cr2O3 system with AI2O3and Cr2O3 diluents were conducted, and the effects of reactionstarting temperature TO, diluents AI2O3 and Cr2O3 on the adiabatic combustion temperature

Keywords： cermet combustion synthesis Al - Cr2sub>O3sub> system thermodynamics reaction model

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The stabilization effect of Al2sub>O3sub> on unconventional Pb/SiO2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10, Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al2sub>O3sub> with a small amount, wasintroduced into Pb/SiO2sub> catalyst in this study.It has been proved that Al2sub>O3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO2sub> catalyst exhibits a much higher stability up to more than 150 h.2sub>O3sub> addition was also proposed.

Keywords： Pb/SiO2sub> Al2sub>O3sub> propane dehydrogenation propene stability

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Feasibility study of plasma sprayed Al2sub>O3sub> coatings as diffusion barrier on CFC

Kirsten BOBZIN, Lidong ZHAO, Nils KOPP, Thomas WARDA

Frontiers of Mechanical Engineering 2012, Volume 7, Issue 4, Pages 371-375 doi: 10.1007/s11465-012-0339-y

Abstract: Within this study the feasibility of plasma sprayed Al2sub>O3sub> coatings as diffusionAl2sub>O3sub> coatings were prepared by air plasma spraying (APS).The results showed that Al2sub>O3sub> could be well deposited onto CFC substrates.temperature of 1270°C, crack network formed within the coating, showing that the plasma sprayed Al2sub>O3sub> coatings are limited regarding to their application temperatures as diffusion

Keywords： diffusion barrier coatings CFC plasma spraying microstructure Al2sub>O3sub>

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Spray Preparation, Microstructure and Properties of Al2sub>O3sub>-Mxsub>O Hard -

Wang Biao,Wang Yudong,Li Huiling,Zhang Zihua

Strategic Study of CAE 2002, Volume 4, Issue 9, Pages 75-80

Abstract: >On carbon steel substrate, base coating of nickel-coated aluminium and intermediate coating of 50% Al2sub>O3sub> + 50% Ni were prepared by means of oxyacetylene spray, and final coating ofAl2sub>O3sub> ～ Mxsub>Oysub> was prepared by means of plasma spray.consisting of 60% (mass) sulphuric acid with 60 % concentration, and 40% (mass) phosphoric ore powder, the Al2sub>O3sub> ～ Mxsub>Oysub> coating resistance to corrosion and wear, is 7.46

Keywords： Al2sub>O3sub>-Mxsub>Oysub> coating plasma resistance to corrosion resistance

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CO2sub> methanation and co-methanation of CO and CO2sub> over Mn-promoted Ni/Al2sub>O3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2, Pages 273-280 doi: 10.1007/s11705-016-1563-5

Abstract: A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnationThe effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanationThe Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperaturescontent was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/AlThe co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the

Keywords： Mn promotion nickel catalysts CO2sub> methanation co-methanation of CO and CO2sub>

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Al2sub>O3sub> and CeO2sub>-promoted MgO sorbents for CO2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1, Pages 83-93 doi: 10.1007/s11705-017-1691-6

Abstract: A series of Al O and CeO modified MgO sorbents was prepared and studied for CO sorption at moderateThe CO sorption capacity of MgO was enhanced with the addition of either Al O or CeO .Over Al O -MgO sorbents, the best capacity of 24.6 mg-CO /g-sorbent was attained at 100 °C, which wascharacterization results, we conclude that the promotion effect on CO sorption with the addition of AlCompared to Al O , CeO is more effective for promoting the CO capacity of MgO.

Keywords： CO2sub> capture MgO sorbents Al2sub>O3sub> CeO2sub> flue gas

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Evaluation of H2sub> on the Evolution Mechanism of NOxsub> Storage and Reductionover Pt–Ba–Ce/γ-Al2sub>O3sub> Catalysts Article

Pan Wang, Jing Yi, Chuan Sun, Peng Luo, Lili Lei

Engineering 2019, Volume 5, Issue 3, Pages 568-575 doi: 10.1016/j.eng.2019.02.005

Abstract:

In this investigation, Pt–Ba–Ce/γ-Al2sub>O3sub> catalysts were preparedThe physical and chemical properties of the Pt–Ba–Ce/γ-Al2sub>O3sub>>xsub>, CeO2sub>, and BaCO3sub>, whose peaks were observed in X-ray diffraction(XRD) spectra, dispersed well on the γ-Al2O3, as shown by transmission electron microscope (TEM>catsub> at 350 °C, which was ascribed to the increase in NO2sub> yield.

Keywords： Pt–Ba–Ce/γ-Al2sub>O3sub> catalysts Physicochemical properties NOxsub> storageand reduction NOxsub> emission H2sub> reductant

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Highly selective catalytic hydrodeoxygenation of guaiacol to cyclohexane over Pt/TiO

Zhong HE,Xianqin WANG

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 3, Pages 369-377 doi: 10.1007/s11705-014-1435-9

Abstract: Catalysts Pt/TiO and NiMo/Al O are highly active and selective for the hydrodeoxygenation of guaiacolNiMo/Al O and Pt/Al O are more active and selective for cyclohexane formation as compared with Pt/TiO

Keywords： Pt/TiO2sub> NiMo/Al2sub>O3sub> Pt/Al2sub>O3sub> bio-oil hydrodeoxygenation

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Fe - Ni - Co - Al2sub>O3sub> Cermets Inert Anode for Aluminum Electrolysis

Qiu Zhuxian,Shi Zhongning,Xu Junli

Strategic Study of CAE 2004, Volume 6, Issue 8, Pages 35-39

Abstract: The cell was built with a graphite cathode of 120 mm×40 mm×20 mm and a Fe - Ni - Co -Al2sub>O3sub> cermet inert anode of 120 mm×80 mm×15 mm.The anode gas consisted of 98%〜99% O2sub> which was analyzed with an Orsat apparatus.confirmed that the electrochemical reaction occurred in the electrolysis cell was the decomposition of Al2sub>O3sub> in the bath and the anode used was inert.

Keywords： aluminum electrolysis inert anode back EMF value

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Effects of Pd doping on N

Mingxin Dong, Jun Wang, Jinxin Zhu, Jianqiang Wang, Wulin Wang, Meiqing Shen

Frontiers of Environmental Science & Engineering 2017, Volume 11, Issue 6, doi: 10.1007/s11783-017-0976-9

Abstract: Three types of catalysts, Pt/BaO/Al O , Pt/Pd mechanical mixing catalyst (Pt/BaO/Al O +Pd/Al O ) andCompared with Pt/BaO/Al O , (Pt/BaO/Al O +Pd/Al O ) produced less N O and more NH during NO storageand reduction process, while an opposite trend was found over (Pt-Pd/BaO/Al O +Al O ).Temperature programmed reactions of NO with H /CO results showed that Pd/Al O component in (Pt/BaO/AlMost of N O formed over (Pt-Pd/BaO/Al O +Al O ) was originated from Pd/BaO/Al O component.

Keywords： NOxsub> storage reduction Pt/BaO/Al2sub>O3sub> Pd doping N2sub>O formation

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Events and reaction mechanisms during the synthesis of an Al

M. ABDELLAHI, M. ZAKERI, H. BAHMANPOUR

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 2, Pages 123-129 doi: 10.1007/s11705-013-1325-6

Abstract: An Al O -TiB nanocomposite was successfully synthesized by the high energy ball milling of Al, B O

Keywords： ball milling nanocomposite Al2sub>O3sub> TiB2sub>

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Effect of SiO

Qian WANG, Lei WANG, Hui WANG, Zengxi LI, Xiangping ZHANG, Suojiang ZHANG, Kebin ZHOU

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 1, Pages 79-88 doi: 10.1007/s11705-010-0550-5

Abstract: A series of SAPO-34 molecular sieves with different SiO /Al O ratios have been synthesized for the methanol-to-olefinwhich show that the crystallinity and particle diameter of SAPO-34 as well as HZSM-5 increase with SiO /Alvariation of BET surface area of SAPO-34 is different from that of HZSM-5 and the sample with SiO /AlWhen the SiO /Al O ratio increases, propylene and butylenes become the predominant product of the MTO

Keywords： HZSM-5 SAPO-34 methanol-to-olefin (MTO) SiO2sub>/Al2sub>O3sub> ratio

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Preparation of Cu/ZnO/Al

Hui FAN, Huayan ZHENG, Zhong LI

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 4, Pages 445-451 doi: 10.1007/s11705-010-0521-x

Abstract: Cu/ZnO/Al O catalysts with Cu/Zn/Al ratios of 6/3/1 were precipitated and aged by conventional and microwaveirradiation on the catalytic performance was investigated to optimize the preparing condition of Cu/ZnO/Al

Keywords： microwave irradiation precipitation temperature aging temperature methanol synthesis Cu/ZnO/Al2sub>O3sub> catalyst

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Rh2sub>O3sub>/hexagonal CePO4sub> nanocatalysts for N2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4, Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords： Rh2sub>O3sub> CePO4sub> N2sub>O decomposition

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Preparation and characterization of alumina hollow fiber membranes

Tao WANG, Yuzhong ZHANG, Guangfen LI, Hong LI

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 3, Pages 265-271 doi: 10.1007/s11705-009-0010-2

Abstract: In this study, the alumina (Al O ) hollow fiber membranes were prepared by a combined phase-inversion, which was then sintered at elevated temperatures in order to obtain the Al O hollow fiber membraneThe dope solution consisted of polyethersulfone (PES), N-methyl-2-pyrrolidone (NMP) and polyvinylpyrrolidoneThe prepared Al O hollow fiber membranes were characterized by a scanning electron microscope (SEM)When the Al O /PES ratio reached 9, the pure water flux and maximum pore size were at 2547 L/m ·h and

Keywords： Al2sub>O3sub> ceramic membranes hollow fiber